List of Contributors xvii
Preface xxiii
Part One Fundamentals 1
1 Overview of Magnetic Nanomaterials 3
Ziyu Yang, Shuang Qiao, Shouheng Sun, and Yanglong Hou
1.1 Introduction 3
1.2 Typical Characterization of Magnetic Nanomaterials 14
1.3 Conclusions 22
References 22
2 Magnetism of Nanomaterials 29
Ralph Skomski, Balamurugan Balasubramanian, and David J. Sellmyer
2.1 Introduction 29
2.2 Nanomagnetic Phenomena of Atomic Origin 48
2.3 Micromagnetics 52
2.4 Spin-Dependent Transport 64
Appendices 71
Appendix 2.A: Functional Derivatives and Materials Equations 71
Appendix 2.B: Relativistic Physics 72
Appendix 2.C: Unit Conversion in Magnetism 74
Acknowledgments 74
References 74
Part Two Synthesis 81
3 Overview of Synthesis of Magnetic Nanomaterials 83
Xin Chu and Yanglong Hou
3.1 Introduction 83
3.2 General Synthesis Mechanism of Magnetic Nanoparticles 85
3.3 Typical Methods and Equipment of Magnetic Nanomaterials Synthetic Techniques: Chemical Approaches 85
3.4 Typical Methods and Equipment of Magnetic Nanomaterials Synthetic Techniques: Physical Approaches 104
3.5 Conclusions and Perspectives 113
References 114
4 Synthesis of Soft Magnetic Nanomaterials and Alloys 121
Song Lan and Matthew A. Willard
4.1 Introduction 121
4.2 Nanoparticles 123
4.3 Nanorods 127
4.4 Thin Films 134
4.5 Ribbons 136
4.6 Conclusions 140
References 141
5 Synthesis of Nanostructured Rare-Earth Permanent Magnets 147
Ming Yue and George C. Hadjipanayis
5.1 Introduction 147
5.2 RCox-Based (R = Sm, Pr, Y, La) Nanostructured Magnets 155
5.3 R2Fe14B-Based (R = Pr, Nd, Tb, Dy) Magnets 161
5.4 Conclusions and Perspectives 166
References 166
6 Synthesis of Rare Earth Free Permanent Magnets 175
Shenqiang Ren and Jinbo Yang
6.1 Introduction 175
6.2 Tetragonal L10 FeCo 175
6.3 MnBi Low-Temperature Phase 179
6.4 Conclusions and Perspective 186
Acknowledgment 187
References 187
7 Synthesis and Properties of Magnetic Chalcogenide Nanostructures 191
Karthik Ramasamy, Soubantika Palchoudhury, and Arunava Gupta
7.1 Introduction 191
7.2 Synthesis Methods of Binary Magnetic Chalcogenide
7.3 Synthesis Methods of Ternary and Higher Order Magnetic
Chalcogenides Nanostructures 201
7.4 Structural and Magnetic Characterizations of Magnetic Chalcogenide Nanostructures 206
7.5 Potential Applications of Magnetic Chalcogenide Nanostructures 208
7.6 Conclusions and Perspectives 211
Acknowledgments 212
References 212
8 Magnetic Multicomponent Heterostructured Nanocrystals 217
P. Davide Cozzoli, Concetta Nobile, Riccardo Scarfiello, Angela Fiore, and Luigi Carbone
8.1 Introduction 217
8.2 Synthesis of Heterostructured Nanocrystals: Basic Concepts and Guiding Criteria 219
8.3 Heterostructures with Core/Shell Geometries 223
8.4 Nanohetero-Oligomer Architectures 245
8.5 Conclusions 266 Acknowledgment 267 References 267
9 Wet-Phase Synthesis of Typical Magnetic Nanoparticles with Controlled Morphologies 291
Jiajia Liu, Jia Liu, Meng Xu, and Jiatao Zhang
9.1 Introduction 291
9.2 Synthesis of Hollow/Porous Magnetic Nanoparticles 303
9.3 Conclusions and Perspectives 317
Acknowledgment 317
References 317
10 Self-Assembly of Co Nanocrystals Self-Assembled in 2D and 3D Superlattices: Chemical and Physical Specific Properties 327 Marie-Paule Pileni
10.1 Introduction 327
10.2 Control of Crystalline Structure of Nanoparticles (Nanocrystallinity) and the Nanocrystal Size 328
10.3 Nano-Kirkendall Effect on Co Nanocrystals: Influence of Size and Nanocrystallinity [51–54] 329
10.4 3D Self-Assemblies of Magnetic Supracrystals: Various Structures and Specific Behaviors 331
10.5 3D Self-Assemblies of Magnetic Supracrystals: Physical Properties 333
10.6 Conclusions 337
Acknowledgment 338
References 338
Part Three Applications 343
11 Magnetic Nanoparticles for Bioseparation, Biosensing, and Regenerative Medicine 345
Yiyuan Han, Min Wang, and Chenjie Xu
11.1 Introduction 345
11.2 Synthesis and Modification of High-Moment Magnetic Nanoparticles 346
11.3 Magnetic Nanomaterials for Bioseparation 347
11.4 Magnetic Nanoparticles for Magnetic Biosensing 354
11.5 Magnetic Nanoparticles for Regenerative Medicine 358
11.6 Challenges and Perspectives 360
References 360
12 Magnetic Nanomaterials for Diagnostics 365
Zijian Zhou and Xiaoyuan Chen
12.1 Introduction 365
12.2 Biocompatibility of Magnetic Nanoparticles 366
12.3 Surface Functionalization of Magnetic Nanomaterials 368
12.4 Magnetic Resonance Imaging (MRI) 372
12.5 Magnetoacoustic Tomography (MAT) 378
12.6 Magnetic Particle Imaging (MPI) 381
12.7 Multimodality Imaging 384
12.8 Conclusions and Perspectives 386
References 387
13 Magnetic Nanomaterials for Therapy 393
Daishun Ling and Taeghwan Hyeon
13.1 Introduction 393
13.2 Imaging-Guided Therapy Using Magnetic Nanomaterials 393
13.3 Magnetic Hyperthermia 407
13.4 Targeted Gene Delivery 419
13.5 Manipulation of Cellular Functions 425
13.6 Conclusions and Perspectives 429
Acknowledgments 431
References 431
14 Magnetic Nanomaterials for Data Storage 439
Jung-Wei Liao, Hong-Wei Zhang, and Chih-Huang Lai
14.1 Introduction: Magnetic Data Storage and its Requirements on Magnetic Nanomaterials 439
14.2 Nanostructured Magnetic Thin Films for Data Storage: Overview of Perpendicular Recording (PMR) Media 442
14.3 Nanostructured Magnetic Thin Films for Data Storage: Overview of FePt Media for Heat-Assisted Magnetic Recording (HAMR) 446
14.4 Monodisperse Magnetic Nanoparticles: Synthesis, Phase Transition, Orientation Control, and Nanocomposites 450
14.5 Patterned Magnetic Nanostructures for Bit Patterned Media Through Bottom-Up Approach: Self-Assembly and Guided Assembly of Block Copolymer 454
14.6 Patterned Magnetic Nanostructures for Bit Patterned Media Through Top-Down Approach: Lithograph 462
14.7 Conclusions and Perspectives 465
References 467
15 Magnetic Nanomaterials for Electromagnetic Wave Absorption 473
Ling Bing Kong, Lie Liu, Zhihong Yang, Sean Li, and Tianshu Zhang
15.1 Introduction 473
15.2 Magnetic Nanosized Powders and Composites 474
15.3 Nanosized Carbon Materials with Magnetic Components 506
15.4 Concluding Remarks 509
References 510
16 Magnetic Nanomaterials for Water Remediation 515
Peirui Liu and Yu Hong
16.1 Introduction 515
16.2 Magnetic Nanomaterials for Adsorption and Removal of Pollutants in Water 516
16.3 Magnetic Nanomaterials for Catalytic Degradation of Wastewater 525
16.4 Magnetic Nanomaterials for Wastewater Resources Recovery 529
16.5 Magnetic Nanomaterials for Monitoring and Analysis Technologies 530
16.6 Conclusion and Perspectives 534
Acknowledgment 535
References 535
Index 547